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Information card for entry 4072999
Preview
Coordinates | 4072999.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C47 H56 B Os P |
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Calculated formula | C47 H56 B Os P |
SMILES | [OsH]123456([P](C(C)C)(C(C)C)C(C)C)([CH](=[CH]1C2)c1ccccc1)[cH]1[cH]3[cH]4[cH]5[cH]61.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | One-Pot Dehydrogenative Addition of Isopropyl to Alkynes Promoted by Osmium: Formation of γ-(η3-Allyl)-α-Alkenylphosphine Derivatives Starting from a Dihydride−Dihydrogen−Triisopropylphosphine Complex |
Authors of publication | Esteruelas, Miguel A.; Hernández, Yohar A.; López, Ana M.; Oliván, Montserrat; Oñate, Enrique |
Journal of publication | Organometallics |
Year of publication | 2007 |
Journal volume | 26 |
Journal issue | 9 |
Pages of publication | 2193 |
a | 11.2407 ± 0.0016 Å |
b | 12.5147 ± 0.0018 Å |
c | 13.4682 ± 0.0019 Å |
α | 87.048 ± 0.002° |
β | 89.732 ± 0.002° |
γ | 87.597 ± 0.002° |
Cell volume | 1890.4 ± 0.5 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 5 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0415 |
Residual factor for significantly intense reflections | 0.0315 |
Weighted residual factors for significantly intense reflections | 0.0517 |
Weighted residual factors for all reflections included in the refinement | 0.0535 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.856 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4072999.html
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