Information card for entry 4073341

Structure parameters

• Formula: C39 H60 N3 Rh Si4 Sn
• Calculated formula: C39 H60 N3 Rh Si4 Sn
• SMILES: [c]12([cH]3[c]4([cH]5[c]6([cH]1[Rh]17823456[CH]2=[CH]1CC[CH]7=[CH]8CC2)C)C)N1[Si](C)(C)[Si]2(C)[Si](C)(C)N(c3cc(cc(c3)C)C)[Sn]1N(c1cc(cc(c1)C)C)[Si]2(C)C
• Title of publication: Flexibly Coordinating Tris(arylamido)stannates as Ligands: A [Rh]+/[Sn]-Zwitterion as an Intermediate in the Formation of Rh−Sn Complexes
• Authors of publication: Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 13
• Pages of publication: 3076
• a: 14.2713 ± 0.0016 Å
• b: 12.397 ± 0.0015 Å
• c: 25.911 ± 0.003 Å
• α: 90°
• β: 102.079 ± 0.003°
• γ: 90°
• Cell volume: 4482.7 ± 0.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0849
• Residual factor for significantly intense reflections: 0.0551
• Weighted residual factors for significantly intense reflections: 0.131
• Weighted residual factors for all reflections included in the refinement: 0.1471
• Goodness-of-fit parameter for all reflections included in the refinement: 0.994
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No