Information card for entry 4074102

Structure parameters

• Formula: C30 H45 O2 P Ru
• Calculated formula: C29.995 H41 O2 P Ru
• Title of publication: Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the CO Double Bond
• Authors of publication: Ogasawara, Masamichi; Sakamoto, Takeshi; Ito, Azumi; Ge, Yonghui; Nakajima, Kiyohiko; Takahashi, Tamotsu; Hayashi, Tamio
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 27
• Pages of publication: 6698
• a: 13.829 ± 0.004 Å
• b: 13.881 ± 0.003 Å
• c: 18.137 ± 0.007 Å
• α: 69.891 ± 0.012°
• β: 81.569 ± 0.013°
• γ: 62.002 ± 0.011°
• Cell volume: 2886.3 ± 1.6 ų
• Cell temperature: 298.1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0537
• Weighted residual factors for all reflections included in the refinement: 0.1218
• Goodness-of-fit parameter for all reflections included in the refinement: 1.46
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No