Information card for entry 4074103

Structure parameters

• Formula: C34 H53 O1.5 P2 Ru
• Calculated formula: C34 H41 O1.52 P2 Ru
• Title of publication: Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the CO Double Bond
• Authors of publication: Ogasawara, Masamichi; Sakamoto, Takeshi; Ito, Azumi; Ge, Yonghui; Nakajima, Kiyohiko; Takahashi, Tamotsu; Hayashi, Tamio
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 27
• Pages of publication: 6698
• a: 11.897 ± 0.003 Å
• b: 16.879 ± 0.004 Å
• c: 17.761 ± 0.006 Å
• α: 90°
• β: 90.759 ± 0.013°
• γ: 90°
• Cell volume: 3566.3 ± 1.7 ų
• Cell temperature: 298.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Residual factor for significantly intense reflections: 0.0615
• Weighted residual factors for all reflections included in the refinement: 0.2074
• Goodness-of-fit parameter for all reflections included in the refinement: 0.994
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No