Information card for entry 4076709

Structure parameters

• Formula: C62 H47 Cl2 O7 Os3 P2 Sb
• Calculated formula: C62 H47 Cl2 O7 Os3 P2 Sb
• SMILES: [Os]12([Os]34([H][Os]([Sb]1(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])[C]14=[C]23C=CC=C1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])C#[O])(C#[O])(C#[O])C#[O].C(Cl)Cl
• Title of publication: Nucleophilic Addition Reactions of the Osmium−Antimony Cluster (μ-H)Os3(CO)9(μ3-C6H4)(μ-SbPh2): Orthometalation of Triphenylphosphine at Ambient Temperature
• Authors of publication: Chen, Guizhu; Deng, Mingli; Lee, Chee Keong; Leong, Weng Kee
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 6
• Pages of publication: 1227
• a: 12.0001 ± 0.0002 Å
• b: 12.7351 ± 0.0001 Å
• c: 20.6397 ± 0.0002 Å
• α: 75.511 ± 0.001°
• β: 82.52°
• γ: 71.545 ± 0.001°
• Cell volume: 2892.37 ± 0.06 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0443
• Residual factor for significantly intense reflections: 0.033
• Weighted residual factors for significantly intense reflections: 0.0781
• Weighted residual factors for all reflections included in the refinement: 0.0855
• Goodness-of-fit parameter for all reflections included in the refinement: 1.186
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No