Information card for entry 4080889

Structure parameters

• Chemical name: Ti(O(CH2CH2NSiMe3)2)(NCNtBu)(NPh2)
• Formula: C27 H45 N5 O Si2 Ti
• Calculated formula: C27 H45 N5 O Si2 Ti
• Title of publication: Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands
• Authors of publication: Unruangsri, Junjuda; Morgan, Hannah; Schwarz, Andrew D.; Schofield, A. Daniel; Mountford, Philip
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 10
• Pages of publication: 3091
• a: 10.5115 ± 0.0001 Å
• b: 11.0721 ± 0.0001 Å
• c: 15.8554 ± 0.0002 Å
• α: 70.7026 ± 0.0005°
• β: 73.1029 ± 0.0005°
• γ: 66.3732 ± 0.0006°
• Cell volume: 1568.72 ± 0.03 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0568
• Residual factor for significantly intense reflections: 0.0398
• Weighted residual factors for all reflections: 0.0622
• Weighted residual factors for significantly intense reflections: 0.0458
• Weighted residual factors for all reflections included in the refinement: 0.0433
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0635
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No