Information card for entry 4080891

Structure parameters

• Chemical name: Ti(O(CH2CH2NSiMe3)(CH2CH2NC(Me)C(Ph)NSiMe3)NPh2
• Formula: C31 H44 N4 O Si2 Ti
• Calculated formula: C31 H44 N4 O Si2 Ti
• SMILES: [Ti]123([O](CCN2C(=C(N1[Si](C)(C)C)c1ccccc1)C)CCN3[Si](C)(C)C)N(c1ccccc1)c1ccccc1
• Title of publication: Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands
• Authors of publication: Unruangsri, Junjuda; Morgan, Hannah; Schwarz, Andrew D.; Schofield, A. Daniel; Mountford, Philip
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 10
• Pages of publication: 3091
• a: 10.0433 ± 0.0002 Å
• b: 19.1205 ± 0.0005 Å
• c: 16.3472 ± 0.0004 Å
• α: 90°
• β: 90.2581 ± 0.0009°
• γ: 90°
• Cell volume: 3139.17 ± 0.13 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0719
• Residual factor for significantly intense reflections: 0.0466
• Weighted residual factors for all reflections: 0.0593
• Weighted residual factors for significantly intense reflections: 0.0483
• Weighted residual factors for all reflections included in the refinement: 0.0462
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1236
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No