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Information card for entry 4082750
Preview
Coordinates | 4082750.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C36 H80 Cl2 P4 Rh2 |
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Calculated formula | C36 H80 Cl2 P4 Rh2 |
SMILES | [Rh]12([Cl][Rh]3([Cl]1)[P](C(C)(C)C)(C(C)(C)C)CC[P]3(C(C)(C)C)C(C)(C)C)[P](C(C)(C)C)(C(C)(C)C)CC[P]2(C(C)(C)C)C(C)(C)C |
Title of publication | Synthesis and Reactivity of Three-Coordinate (dtbpe)Rh Silylamides: CO2Bond Cleavage by a Rhodium(I) Disilylamide |
Authors of publication | Whited, Matthew T.; Kosanovich, Alex J.; Janzen, Daron E. |
Journal of publication | Organometallics |
Year of publication | 2014 |
Journal volume | 33 |
Journal issue | 6 |
Pages of publication | 1416 |
a | 11.1131 ± 0.0011 Å |
b | 31.692 ± 0.003 Å |
c | 13.1717 ± 0.0013 Å |
α | 90° |
β | 109.328 ± 0.008° |
γ | 90° |
Cell volume | 4377.6 ± 0.8 Å3 |
Cell temperature | 173 ± 2 K |
Ambient diffraction temperature | 173 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0534 |
Residual factor for significantly intense reflections | 0.0377 |
Weighted residual factors for significantly intense reflections | 0.0635 |
Weighted residual factors for all reflections included in the refinement | 0.0669 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.106 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4082750.html
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