Information card for entry 4082751

Structure parameters

• Formula: C24 H58 N P2 Rh Si2
• Calculated formula: C24 H58 N P2 Rh Si2
• SMILES: C(C)(C)(C)[P]1(C(C)(C)C)CC[P]([Rh]1N([Si](C)(C)C)[Si](C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Synthesis and Reactivity of Three-Coordinate (dtbpe)Rh Silylamides: CO2Bond Cleavage by a Rhodium(I) Disilylamide
• Authors of publication: Whited, Matthew T.; Kosanovich, Alex J.; Janzen, Daron E.
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 6
• Pages of publication: 1416
• a: 20.456 ± 0.004 Å
• b: 17.299 ± 0.003 Å
• c: 9.0187 ± 0.0017 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3191.4 ± 1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 6
• Space group number: 52
• Hermann-Mauguin space group symbol: P n n a
• Hall space group symbol: -P 2a 2bc
• Residual factor for all reflections: 0.043
• Residual factor for significantly intense reflections: 0.0319
• Weighted residual factors for significantly intense reflections: 0.0686
• Weighted residual factors for all reflections included in the refinement: 0.0728
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No