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Information card for entry 4083448
Preview
Coordinates | 4083448.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C147 H161 Au6 Cl O5 P6 |
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Calculated formula | C147 H156 Au6 Cl O5 P6 |
SMILES | [Au]123[Au]456([Au]78[Au]914([Au]125[Au]679[P](c2c4Oc5c([P]1(c1cc(cc(c1)C)C)c1cc(cc(c1)C)C)cccc5C(c4ccc2)(C)C)(c1cc(cc(c1)C)C)c1cc(cc(c1)C)C)[P](c1c2Oc4c([P]8(c5cc(cc(c5)C)C)c5cc(cc(c5)C)C)cccc4C(c2ccc1)(C)C)(c1cc(cc(c1)C)C)c1cc(cc(c1)C)C)[P](c1c2Oc4c([P]3(c3cc(cc(c3)C)C)c3cc(cc(c3)C)C)cccc4C(c2ccc1)(C)C)(c1cc(cc(c1)C)C)c1cc(cc(c1)C)C.[Cl-].O=C(C)CC(O)(C)C |
Title of publication | Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex |
Authors of publication | Ito, Hajime; Saito, Tomohisa; Miyahara, Takahiro; Zhong, Chongmin; Sawamura, Masaya |
Journal of publication | Organometallics |
Year of publication | 2009 |
Journal volume | 28 |
Journal issue | 16 |
Pages of publication | 4829 |
a | 20.1779 ± 0.0004 Å |
b | 22.5012 ± 0.0004 Å |
c | 36.3862 ± 0.0007 Å |
α | 90° |
β | 93.6617 ± 0.0007° |
γ | 90° |
Cell volume | 16486.6 ± 0.5 Å3 |
Cell temperature | 93.1 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for significantly intense reflections | 0.0576 |
Weighted residual factors for all reflections included in the refinement | 0.1663 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.094 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4083448.html
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