Information card for entry 4085215

Structure parameters

• Common name: 10 in manuscript
• Formula: C26 H46 B F4 N2 P2 Rh
• Calculated formula: C26 H46 B F4 N2 P2 Rh
• SMILES: [Rh]1234([P](c5n([P]1(C(C)(C)C)C(C)(C)C)ccn5)(C(C)(C)C)C(C)(C)C)[CH]1=[CH]2C2[CH]3=[CH]4C1C2.[B](F)(F)(F)[F-]
• Title of publication: 1,2-Bis(di-tert-butylphosphino)imidazole (dtbpi): A Versatile Imidazole-Based, Rigid, Bulky Bisphosphine Ligand for Transition Metals
• Authors of publication: Brill, Marcel; Rominger, Frank; Hofmann, Peter
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 2
• Pages of publication: 506
• a: 8.8341 ± 0.0018 Å
• b: 21.44 ± 0.004 Å
• c: 15.5 ± 0.003 Å
• α: 90°
• β: 92.43 ± 0.004°
• γ: 90°
• Cell volume: 2933.1 ± 1 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 7
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0618
• Residual factor for significantly intense reflections: 0.0478
• Weighted residual factors for significantly intense reflections: 0.0904
• Weighted residual factors for all reflections included in the refinement: 0.0977
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No