Information card for entry 4085470

Structure parameters

• Chemical name: Sn(C(Ph)C(H)B(L))(N(SiMe3)(Dipp))
• Formula: C54.25 H79.38 B N3 Si Sn
• Calculated formula: C54.25 H79.375 B N3 Si Sn
• Title of publication: Reactivity of Boryl- and Silyl-Substituted Carbenoids toward Alkynes: Insertion and Cycloaddition Chemistry
• Authors of publication: Protchenko, Andrey V.; Blake, Matthew P.; Schwarz, Andrew D.; Jones, Cameron; Mountford, Philip; Aldridge, Simon
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2126
• a: 9.4466 ± 0.0003 Å
• b: 16.5433 ± 0.0006 Å
• c: 18.3415 ± 0.0006 Å
• α: 81.69 ± 0.003°
• β: 76.404 ± 0.003°
• γ: 77.944 ± 0.003°
• Cell volume: 2710.83 ± 0.16 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0288
• Residual factor for significantly intense reflections: 0.0272
• Weighted residual factors for all reflections: 0.0053
• Weighted residual factors for significantly intense reflections: 0.0052
• Weighted residual factors for all reflections included in the refinement: 0.0052
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1758
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No