Information card for entry 4085471

Structure parameters

• Chemical name: {Sn(N(Dipp)SiMe3)(CCPh)}2
• Formula: C46 H62 N2 Si2 Sn2
• Calculated formula: C46 H62 N2 Si2 Sn2
• SMILES: [C]1(#Cc2ccccc2)[Sn]([C](#Cc2ccccc2)[Sn]1N(c1c(cccc1C(C)C)C(C)C)[Si](C)(C)C)N(c1c(cccc1C(C)C)C(C)C)[Si](C)(C)C
• Title of publication: Reactivity of Boryl- and Silyl-Substituted Carbenoids toward Alkynes: Insertion and Cycloaddition Chemistry
• Authors of publication: Protchenko, Andrey V.; Blake, Matthew P.; Schwarz, Andrew D.; Jones, Cameron; Mountford, Philip; Aldridge, Simon
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2126
• a: 12.01113 ± 0.00011 Å
• b: 14.37422 ± 0.0001 Å
• c: 14.20295 ± 0.00011 Å
• α: 90°
• β: 111.466 ± 0.0009°
• γ: 90°
• Cell volume: 2282.05 ± 0.03 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0195
• Residual factor for significantly intense reflections: 0.0188
• Weighted residual factors for all reflections: 0.0184
• Weighted residual factors for significantly intense reflections: 0.0183
• Weighted residual factors for all reflections included in the refinement: 0.0182
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0565
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No