Information card for entry 4085676

Structure parameters

• Formula: C36 H54 F P3 Si
• Calculated formula: C36 H54 F P3 Si
• SMILES: P(C(C)C)(C(C)C)c1ccccc1[Si](F)(c1c(P(C(C)C)C(C)C)cccc1)c1ccccc1P(C(C)C)C(C)C
• Title of publication: Coordination of a Triphosphine‒Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction
• Authors of publication: Gualco, Pauline; Mallet-Ladeira, Sonia; Kameo, Hajime; Nakazawa, Hiroshi; Mercy, Maxime; Maron, Laurent; Amgoune, Abderrahmane; Bourissou, Didier
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1449
• a: 11.6777 ± 0.0003 Å
• b: 16.5067 ± 0.0005 Å
• c: 20.5065 ± 0.0006 Å
• α: 68.907 ± 0.002°
• β: 86.595 ± 0.002°
• γ: 84.295 ± 0.002°
• Cell volume: 3668.53 ± 0.19 ų
• Cell temperature: 193 K
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1354
• Residual factor for significantly intense reflections: 0.0495
• Weighted residual factors for significantly intense reflections: 0.0944
• Weighted residual factors for all reflections included in the refinement: 0.1263
• Goodness-of-fit parameter for all reflections included in the refinement: 0.982
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No