Information card for entry 4085677

Structure parameters

• Formula: C36 H54 Au Cl F P3 Si
• Calculated formula: C36 H54 Au Cl F P3 Si
• SMILES: [Au]([P](c1c([Si]23F)cccc1)(C(C)C)C(C)C)([P](c1c2cccc1)(C(C)C)C(C)C)[P](c1c3cccc1)(C(C)C)C(C)C.[Cl-]
• Title of publication: Coordination of a Triphosphine‒Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au+→Si Interaction
• Authors of publication: Gualco, Pauline; Mallet-Ladeira, Sonia; Kameo, Hajime; Nakazawa, Hiroshi; Mercy, Maxime; Maron, Laurent; Amgoune, Abderrahmane; Bourissou, Didier
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1449
• a: 11.8818 ± 0.0004 Å
• b: 11.8818 ± 0.0004 Å
• c: 49.134 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 6007.3 ± 0.5 ų
• Cell temperature: 193 K
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 7
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3 :H
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.04
• Residual factor for significantly intense reflections: 0.0371
• Weighted residual factors for significantly intense reflections: 0.081
• Weighted residual factors for all reflections included in the refinement: 0.0823
• Goodness-of-fit parameter for all reflections included in the refinement: 1.077
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No