Information card for entry 4085912

Structure parameters

• Formula: C45 H51 F6 P3 Pt3 Si3
• Calculated formula: C45 H51 F6 P3 Pt3 Si3
• SMILES: [Pt]123([Pt]4([Pt]1([P](C)(C)C)([Si]4(c1ccc(F)cc1)c1ccc(F)cc1)[Si]2(c1ccc(F)cc1)c1ccc(F)cc1)([P](C)(C)C)[Si]3(c1ccc(F)cc1)c1ccc(F)cc1)[P](C)(C)C
• Title of publication: Ring Expansion of Cyclic Triplatinum(0) Silylene Complexes Induced by Insertion of Alkyne into a Si‒Pt Bond
• Authors of publication: Tanaka, Kimiya; Kamono, Megumi; Tanabe, Makoto; Osakada, Kohtaro
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 12
• Pages of publication: 2985
• a: 14.329 ± 0.002 Å
• b: 27.885 ± 0.003 Å
• c: 12.582 ± 0.002 Å
• α: 90°
• β: 101.772 ± 0.007°
• γ: 90°
• Cell volume: 4921.6 ± 1.2 ų
• Cell temperature: 153 K
• Ambient diffraction temperature: 153 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.068
• Residual factor for significantly intense reflections: 0.0509
• Weighted residual factors for significantly intense reflections: 0.122
• Weighted residual factors for all reflections included in the refinement: 0.1336
• Goodness-of-fit parameter for all reflections included in the refinement: 1.112
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No