Information card for entry 4085913

Structure parameters

• Formula: C51 H63 O4 P3 Pt3 Si3
• Calculated formula: C51 H63 O4 P3 Pt3 Si3
• SMILES: [Pt]12([Pt]34([Pt]([P](C)(C)C)([Si]13(C(=C([Si]2(c1ccccc1)c1ccccc1)C(=O)OC)C(=O)OC)c1ccccc1)[Si]4(c1ccccc1)c1ccccc1)[P](C)(C)C)([P](C)(C)C)c1ccccc1
• Title of publication: Ring Expansion of Cyclic Triplatinum(0) Silylene Complexes Induced by Insertion of Alkyne into a Si‒Pt Bond
• Authors of publication: Tanaka, Kimiya; Kamono, Megumi; Tanabe, Makoto; Osakada, Kohtaro
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 12
• Pages of publication: 2985
• a: 10.6806 ± 0.0008 Å
• b: 14.1926 ± 0.0013 Å
• c: 18.4748 ± 0.0019 Å
• α: 94.415 ± 0.004°
• β: 91.401 ± 0.003°
• γ: 108.193 ± 0.003°
• Cell volume: 2649.1 ± 0.4 ų
• Cell temperature: 153 K
• Ambient diffraction temperature: 153 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0529
• Residual factor for significantly intense reflections: 0.041
• Weighted residual factors for significantly intense reflections: 0.0965
• Weighted residual factors for all reflections included in the refinement: 0.1044
• Goodness-of-fit parameter for all reflections included in the refinement: 1.106
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No