Information card for entry 4085914

Structure parameters

• Formula: C57 H63 F6 O8 P3 Pt3 Si3
• Calculated formula: C57 H63 F6 O8 P3 Pt3 Si3
• SMILES: [Pt]1([Pt]23([Si](c4ccc(F)cc4)(C(=C([Si]2(c2ccc(F)cc2)c2ccc(F)cc2)C(=O)OC)C(=O)OC)c2ccc(F)cc2)C21[C]13[Pt]([P](C)(C)C)([Si](OC=1OC)(c1ccc(F)cc1)c1ccc(F)cc1)[O]=C2OC)([P](C)(C)C)[P](C)(C)C
• Title of publication: Ring Expansion of Cyclic Triplatinum(0) Silylene Complexes Induced by Insertion of Alkyne into a Si‒Pt Bond
• Authors of publication: Tanaka, Kimiya; Kamono, Megumi; Tanabe, Makoto; Osakada, Kohtaro
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 12
• Pages of publication: 2985
• a: 24.239 ± 0.003 Å
• b: 12.6686 ± 0.0014 Å
• c: 22.217 ± 0.003 Å
• α: 90°
• β: 113.336 ± 0.001°
• γ: 90°
• Cell volume: 6264.2 ± 1.3 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.046
• Residual factor for significantly intense reflections: 0.0296
• Weighted residual factors for significantly intense reflections: 0.0822
• Weighted residual factors for all reflections included in the refinement: 0.0975
• Goodness-of-fit parameter for all reflections included in the refinement: 0.717
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No