Information card for entry 4086159

Structure parameters

• Formula: C92 H102 Ge2 N4 O2 Si2
• Calculated formula: C92 H102 Ge2 N4 O2 Si2
• SMILES: c1(c(cc(cc1C(c1ccccc1)c1ccccc1)C)C(c1ccccc1)c1ccccc1)N([Ge]N(c1ccccc1)N(c1ccccc1)[Ge]N(c1c(cc(cc1C(c1ccccc1)c1ccccc1)C)C(c1ccccc1)c1ccccc1)[Si](C)(C)C)[Si](C)(C)C.O(CC)CC.O(CC)CC
• Title of publication: Reactivity of Amido-Digermynes, LGeGeL (L = Bulky Amide), toward Olefins and Related Molecules: Facile Reduction, C–H Activation, and Reversible Cycloaddition of Unsaturated Substrates
• Authors of publication: Hadlington, Terrance J.; Li, Jiaye; Hermann, Markus; Davey, Amelia; Frenking, Gernot; Jones, Cameron
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 13
• Pages of publication: 3175
• a: 32.6327 ± 0.0012 Å
• b: 13.2336 ± 0.0004 Å
• c: 20.1143 ± 0.0008 Å
• α: 90°
• β: 113.787 ± 0.004°
• γ: 90°
• Cell volume: 7948.4 ± 0.6 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0659
• Residual factor for significantly intense reflections: 0.0459
• Weighted residual factors for significantly intense reflections: 0.1209
• Weighted residual factors for all reflections included in the refinement: 0.1319
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No