Information card for entry 4086365

Structure parameters

• Formula: C22 H48 Cl2 Os P2
• Calculated formula: C22 H48 Cl2 Os P2
• SMILES: C(=C(C)C)=[Os]([P](C(C)C)(C(C)C)C(C)C)(Cl)([P](C(C)C)(C(C)C)C(C)C)Cl
• Title of publication: Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes.
• Authors of publication: Casanova, Noelia; Esteruelas, Miguel A.; Gulías, Moisés; Larramona, Carmen; Mascareñas, José L; Oñate, Enrique
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 2
• Pages of publication: 91 - 99
• a: 21.184 ± 0.003 Å
• b: 9.6719 ± 0.0013 Å
• c: 16.227 ± 0.002 Å
• α: 90°
• β: 125.504 ± 0.002°
• γ: 90°
• Cell volume: 2706.6 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0231
• Residual factor for significantly intense reflections: 0.0213
• Weighted residual factors for significantly intense reflections: 0.0477
• Weighted residual factors for all reflections included in the refinement: 0.0484
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No