Information card for entry 4087982

Structure parameters

• Formula: C103 H126 Mo2 N8 O10 P2 Si2
• Calculated formula: C103 H126 Mo2 N8 O10 P2 Si2
• Title of publication: Transition Metal Complexes of a “Half-Parent” Phosphasilene Adduct Representing Silylene→Phosphinidene→Metal Complexes
• Authors of publication: Hansen, Kerstin; Szilvási, Tibor; Blom, Burgert; Driess, Matthias
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 24
• Pages of publication: 5703
• a: 15.9982 ± 0.0013 Å
• b: 20.0928 ± 0.0008 Å
• c: 17.7845 ± 0.001 Å
• α: 90°
• β: 114.755 ± 0.009°
• γ: 90°
• Cell volume: 5191.5 ± 0.7 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1237
• Residual factor for significantly intense reflections: 0.0741
• Weighted residual factors for significantly intense reflections: 0.1612
• Weighted residual factors for all reflections included in the refinement: 0.1936
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No