Information card for entry 4089321

Structure parameters

• Common name: [Sn(iPr)(O2CCF3){(Me3Si)2CSiMe2CH2CH2SiMe2C(SiMe3)2}]
• Formula: C25 H59 F3 O2 Si6 Sn
• Calculated formula: C25 H59 F3 O2 Si6 Sn
• SMILES: [Sn]1(OC(=O)C(F)(F)F)(C([Si](C)(C)CC[Si](C1([Si](C)(C)C)[Si](C)(C)C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C(C)C
• Title of publication: Reactions of a Highly Crowded Cyclic Stannylene with Iodoalkanes, Enones, and Dienes. Inhibition of Nucleophilic Substitution at Tin(IV) Centers
• Authors of publication: Asadi, Ashrafolmolouk; Eaborn, Colin; Hill, Michael S.; Hitchcock, Peter B.; Meehan, Margaret M.; Smith, J. David
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 12
• Pages of publication: 2430
• a: 9.5492 ± 0.0002 Å
• b: 44.979 ± 0.002 Å
• c: 17.0348 ± 0.0008 Å
• α: 90°
• β: 92.488 ± 0.003°
• γ: 90°
• Cell volume: 7309.8 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1175
• Residual factor for significantly intense reflections: 0.0595
• Weighted residual factors for significantly intense reflections: 0.1151
• Weighted residual factors for all reflections included in the refinement: 0.1344
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No