Information card for entry 4102349

Structure parameters

• Formula: C30 H69 B2 Cl O4 Os P2
• Calculated formula: C30 H69 B2 Cl O4 Os P2
• SMILES: [OsH2]1([H][B]1OC(C)(C)C(OB1OC(C)(C)C(O1)(C)C)(C)C)(Cl)([P](C(C)C)(C(C)C)C(C)C)[P](C(C)C)(C(C)C)C(C)C
• Title of publication: Borinium Cations as σ-B-H Ligands in Osmium Complexes
• Authors of publication: Miguel A. Esteruelas; Francisco J. Fernández-Alvarez; Ana M. López; Malka Mora; Enrique Oñate
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2010
• Journal volume: 132
• Pages of publication: 5600 - 5601
• a: 14.005 ± 0.002 Å
• b: 10.5978 ± 0.0018 Å
• c: 26.244 ± 0.004 Å
• α: 90°
• β: 101.324 ± 0.003°
• γ: 90°
• Cell volume: 3819.4 ± 1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.09
• Residual factor for significantly intense reflections: 0.0463
• Weighted residual factors for significantly intense reflections: 0.0746
• Weighted residual factors for all reflections included in the refinement: 0.0849
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No