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Information card for entry 4105124
Preview
Coordinates | 4105124.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C19 H36 O2 Si |
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Calculated formula | C19 H36 O2 Si |
SMILES | [Si]1(OCC2CCC[C@@H]([C@H](O1)C(C)C)C=2)(C(C)(C)C)C(C)(C)C.[Si]1(OCC2CCC[C@H]([C@@H](O1)C(C)C)C=2)(C(C)(C)C)C(C)(C)C |
Title of publication | Insertions of Silylenes into Vinyl Epoxides: Diastereoselective Synthesis of Functionalized, Optically Active trans-Dioxasilacyclooctenes |
Authors of publication | Michel Prévost; K. A. Woerpel |
Journal of publication | Journal of the American Chemical Society |
Year of publication | 2009 |
Journal volume | 131 |
Pages of publication | 14182 - 14183 |
a | 12.9471 ± 0.0005 Å |
b | 10.05 ± 0.0004 Å |
c | 14.9118 ± 0.0006 Å |
α | 90° |
β | 101.843 ± 0.0004° |
γ | 90° |
Cell volume | 1898.99 ± 0.13 Å3 |
Cell temperature | 103 ± 2 K |
Ambient diffraction temperature | 103 ± 2 K |
Number of distinct elements | 4 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0335 |
Residual factor for significantly intense reflections | 0.0304 |
Weighted residual factors for significantly intense reflections | 0.0832 |
Weighted residual factors for all reflections included in the refinement | 0.0861 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.049 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4105124.html
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