Information card for entry 4105452

Structure parameters

• Formula: C18 H40 Cl8 Ga2 P4
• Calculated formula: C18 H40 Cl8 Ga2 P4
• SMILES: [Ga](Cl)(Cl)([Cl-])Cl.[Ga]([Cl-])(Cl)(Cl)Cl.[P+](P(P([P+](C)(C)C)C1CCCCC1)C1CCCCC1)(C)(C)C
• Title of publication: New Synthetic Procedures to Catena-Phosphorus Cations: Preparation and Dissociation of the First cyclo-Phosphino-halophosphonium Salts
• Authors of publication: Jan J. Weigand; Neil Burford; Reagan J. Davidson; T. Stanley Cameron; Patrick Seelheim
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 17943 - 17953
• a: 9.74 ± 0.002 Å
• b: 12.396 ± 0.003 Å
• c: 28.66 ± 0.007 Å
• α: 90°
• β: 90.19 ± 0.01°
• γ: 90°
• Cell volume: 3460.3 ± 1.4 ų
• Cell temperature: 123.1 K
• Ambient diffraction temperature: 123.1 ± 0.2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0662
• Weighted residual factors for all reflections included in the refinement: 0.1876
• Goodness-of-fit parameter for all reflections included in the refinement: 1.089
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No