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Information card for entry 4108965
Preview
Coordinates | 4108965.cif |
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Original paper (by DOI) | HTML |
Formula | C22 H34 O4 Rh2 S2 |
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Calculated formula | C22 H34 O3.98 Rh2 S2 |
Title of publication | Photochromism of an Organorhodium Dithionite Complex in the Crystalline-State: Molecular Motion of Pentamethylcyclopentadienyl Ligands Coupled to Atom Rearrangement in a Dithionite Ligand |
Authors of publication | Hidetaka Nakai; Takashi Nonaka; Yousuke Miyano; Motohiro Mizuno; Yoshiki Ozawa; Koshiro Toriumi; Nobuaki Koga; Takanori Nishioka; Masahiro Irie; Kiyoshi Isobe |
Journal of publication | Journal of the American Chemical Society |
Year of publication | 2008 |
Journal volume | 130 |
Pages of publication | 17836 - 17845 |
a | 8.3642 ± 0.0004 Å |
b | 36.67 ± 0.002 Å |
c | 8.4039 ± 0.0004 Å |
α | 90° |
β | 115.267 ± 0.002° |
γ | 90° |
Cell volume | 2331 ± 0.2 Å3 |
Cell temperature | 110.2 K |
Sample thermal history | photo irradiation for 190h at 110K and keep in the dark for 84h at 293K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for significantly intense reflections | 0.0755 |
Weighted residual factors for all reflections included in the refinement | 0.2092 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.08 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4108965.html
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