Information card for entry 4113509

Structure parameters

• Formula: C41.5 H40 Al Cl5 Co N O3 P2
• Calculated formula: C41.44 H39.95 Al Cl5 Co N O3 P2
• Title of publication: A Thermally Stable and Sterically Unprotected Terminal Electrophilic Phosphinidene Complex of Cobalt and Its Conversion to an η1-Phosphirene
• Authors of publication: Javier Sánchez-Nieves; Brian T. Sterenberg; Konstantin A. Udachin; Arthur J. Carty
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 2404 - 2405
• a: 12.3668 ± 0.0005 Å
• b: 13.0461 ± 0.0006 Å
• c: 15.9147 ± 0.0007 Å
• α: 88.193 ± 0.001°
• β: 75.292 ± 0.001°
• γ: 73.836 ± 0.001°
• Cell volume: 2383.22 ± 0.18 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0791
• Residual factor for significantly intense reflections: 0.0487
• Weighted residual factors for significantly intense reflections: 0.165
• Weighted residual factors for all reflections included in the refinement: 0.1794
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No