Information card for entry 4115162

Structure parameters

• Chemical name: 4-Methyl-2-N,N-bis(t-butyldimethylsilyloxy)amino-3-trimethylsilyloxy-pent-1-ene
• Formula: C21 H49 N O3 Si3
• Calculated formula: C21 H49 N O3 Si3
• SMILES: [Si](ON(C(=C)C(O[Si](C)(C)C)C(C)C)O[Si](C)(C)C(C)(C)C)(C)(C)C(C)(C)C
• Title of publication: Structure and Stereodynamics of N,N-Bis(silyloxy)enamines
• Authors of publication: Alexander A. Tishkov; Alexander D. Dilman; Valery I. Faustov; Arsenij A. Birukov; Konstantin S. Lysenko; Paul A. Belyakov; Sema L. Ioffe; Yury A. Strelenko; Michael Yu. Antipin
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 11358 - 11367
• a: 11.961 ± 0.003 Å
• b: 10.926 ± 0.003 Å
• c: 22.229 ± 0.006 Å
• α: 90°
• β: 102.837 ± 0.007°
• γ: 90°
• Cell volume: 2832.4 ± 1.3 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0763
• Residual factor for significantly intense reflections: 0.0528
• Weighted residual factors for significantly intense reflections: 0.1293
• Weighted residual factors for all reflections included in the refinement: 0.1457
• Goodness-of-fit parameter for all reflections included in the refinement: 0.984
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No