Information card for entry 4115163

Structure parameters

• Chemical name: 4-Methyl-2-N,N-bis(t-butyldimethylsilyloxy)amino-3-trimethylsilyloxy-pent-1-ene
• Formula: C20 H36 N2 O4 Si2
• Calculated formula: C20 H36 N2 O4 Si2
• SMILES: [Si](ON(O[Si](C)(C)C(C)(C)C)/C=C/c1ccc(N(=O)=O)cc1)(C)(C)C(C)(C)C
• Title of publication: Structure and Stereodynamics of N,N-Bis(silyloxy)enamines
• Authors of publication: Alexander A. Tishkov; Alexander D. Dilman; Valery I. Faustov; Arsenij A. Birukov; Konstantin S. Lysenko; Paul A. Belyakov; Sema L. Ioffe; Yury A. Strelenko; Michael Yu. Antipin
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 11358 - 11367
• a: 12.149 ± 0.004 Å
• b: 14.155 ± 0.004 Å
• c: 14.586 ± 0.005 Å
• α: 90°
• β: 100.34 ± 0.03°
• γ: 90°
• Cell volume: 2467.6 ± 1.4 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0977
• Residual factor for significantly intense reflections: 0.0463
• Weighted residual factors for significantly intense reflections: 0.1042
• Weighted residual factors for all reflections included in the refinement: 0.1117
• Goodness-of-fit parameter for all reflections included in the refinement: 0.852
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No