Information card for entry 4116240

Structure parameters

• Formula: C31 H34 N2 O2 Si W
• Calculated formula: C31 H33 N2 O2 Si W
• Title of publication: Synthesis, Structure, and Silylene Exchange Reaction of Base-Stabilized Hydrido(silylene)tungsten Complexes and Rearrangement of Hydrosilyl(pyridine)tungsten Complexes to the Base-Stabilized Hydrido(silylene) Complexes via 1,2-Hydrogen Migration
• Authors of publication: Hiroyuki Sakaba; Masanori Tsukamoto; Takeshi Hirata; Chizuko Kabuto; Hiroshi Horino
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2000
• Journal volume: 122
• Pages of publication: 11511 - 11512
• a: 9.018 ± 0.002 Å
• b: 16.244 ± 0.004 Å
• c: 20.737 ± 0.002 Å
• α: 90°
• β: 90.84 ± 0.01°
• γ: 90°
• Cell volume: 3037.4 ± 1 ų
• Cell temperature: 286.2 K
• Ambient diffraction temperature: 286.2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0422
• Residual factor for significantly intense reflections: 0.0422
• Weighted residual factors for significantly intense reflections: 0.066
• Weighted residual factors for all reflections included in the refinement: 0.066
• Goodness-of-fit parameter for all reflections included in the refinement: 1.553
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No