Information card for entry 4116241

Structure parameters

• Formula: C29 H31 N O2 Si W
• Calculated formula: C29 H31 N O2 Si W
• Title of publication: Synthesis, Structure, and Silylene Exchange Reaction of Base-Stabilized Hydrido(silylene)tungsten Complexes and Rearrangement of Hydrosilyl(pyridine)tungsten Complexes to the Base-Stabilized Hydrido(silylene) Complexes via 1,2-Hydrogen Migration
• Authors of publication: Hiroyuki Sakaba; Masanori Tsukamoto; Takeshi Hirata; Chizuko Kabuto; Hiroshi Horino
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2000
• Journal volume: 122
• Pages of publication: 11511 - 11512
• a: 34.226 ± 0.009 Å
• b: 20.44 ± 0.01 Å
• c: 15.638 ± 0.007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 10940 ± 8 ų
• Cell temperature: 286.2 K
• Ambient diffraction temperature: 286.2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0511
• Residual factor for significantly intense reflections: 0.0511
• Weighted residual factors for significantly intense reflections: 0.0541
• Weighted residual factors for all reflections included in the refinement: 0.0541
• Goodness-of-fit parameter for all reflections included in the refinement: 2.492
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No