Information card for entry 4116680

Structure parameters

• Chemical name: Bis(acetylacetonato)(2-vinyl-N,N-dimethylaniline)ruthenium(III) hexafluoroantimonate
• Formula: C20 H27 F6 N O4 Ru Sb
• Calculated formula: C20 H27 F6 N O4 Ru Sb
• SMILES: [Sb](F)(F)(F)(F)(F)[F-].[Ru]1234(OC(=CC(=[O]1)C)C)(OC(=CC(=[O]2)C)C)[N](C)(C)c1ccccc1[CH]3=[CH2]4
• Title of publication: Alkene Complexes of Divalent and Trivalent Ruthenium Stabilized by Chelation. Dependence of Coordinated Alkene Orientation on Metal Oxidation State
• Authors of publication: Martin A. Bennett; Graham A. Heath; David C. R. Hockless; Ivan Kovacik; Anthony C. Willis
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 1998
• Journal volume: 120
• Pages of publication: 932 - 941
• a: 9.125 ± 0.003 Å
• b: 11.929 ± 0.004 Å
• c: 12.567 ± 0.003 Å
• α: 81.73 ± 0.02°
• β: 82.03 ± 0.02°
• γ: 70.75 ± 0.02°
• Cell volume: 1271.9 ± 0.7 ų
• Cell temperature: 293.2 K
• Ambient diffraction temperature: 293.2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.036
• Weighted residual factors for significantly intense reflections: 0.036
• Goodness-of-fit parameter for significantly intense reflections: 1.16
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No