Information card for entry 4117159

Structure parameters

• Common name: OsO4-diamine complex
• Chemical name: Osmium tetraoxide - (R,R)-trans-1,2-bispyrollidinecyclohexane complex
• Formula: C14 H26 N2 O4 Os
• Calculated formula: C14 H26 N2 O4 Os
• SMILES: [Os]1(=O)(=O)(=O)(=O)[N]2([C@@H]3CCCC[C@H]3[N]31CCCC3)CCCC2
• Title of publication: X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine-OsO4 Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO4
• Authors of publication: E. J. Corey; Sepehr Sarshar; Mihai D. Azimioara; Ronald C. Newbold; Mark C. Noe
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 1996
• Journal volume: 118
• Pages of publication: 7851 - 7852
• a: 10.987 ± 0.003 Å
• b: 11.25 ± 0.002 Å
• c: 12.389 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1531.3 ± 0.6 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0534
• Residual factor for significantly intense reflections: 0.0441
• Weighted residual factors for all reflections: 0.1114
• Weighted residual factors for significantly intense reflections: 0.1041
• Goodness-of-fit parameter for all reflections: 1.003
• Goodness-of-fit parameter for significantly intense reflections: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No