Information card for entry 4122690

Structure parameters

• Formula: C29 H42 Br N3 Si
• Calculated formula: C29 H42 Br N3 Si
• SMILES: [Si]1(Br)(N(C(=C)C=C(N1c1c(cccc1C(C)C)C(C)C)C)c1c(cccc1C(C)C)C(C)C)N
• Title of publication: An Amplified Ylidic "Half-Parent" Iminosilane LSi═NH.
• Authors of publication: Hansen, Kerstin; Szilvási, Tibor; Blom, Burgert; Driess, Matthias
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 40
• Pages of publication: 14207
• a: 20.2447 ± 0.0002 Å
• b: 13.0816 ± 0.0001 Å
• c: 23.9262 ± 0.0003 Å
• α: 90°
• β: 112.898 ± 0.001°
• γ: 90°
• Cell volume: 5837.13 ± 0.11 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0428
• Residual factor for significantly intense reflections: 0.0395
• Weighted residual factors for significantly intense reflections: 0.0989
• Weighted residual factors for all reflections included in the refinement: 0.1011
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No