Information card for entry 4123153

Structure parameters

• Formula: C24 H52 P4 Si2 W
• Calculated formula: C24 H52 P4 Si2 W
• SMILES: [WH3]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[SiH2][SiH](c1ccccc1)c1ccccc1
• Title of publication: σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η(2)-CH2PMe2)H with Phenylsilanes.
• Authors of publication: Zuzek, Ashley A.; Neary, Michelle C.; Parkin, Gerard
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Pages of publication: 141217070549000
• a: 9.7561 ± 0.0009 Å
• b: 16.1203 ± 0.0015 Å
• c: 10.2677 ± 0.001 Å
• α: 90°
• β: 93.0754 ± 0.0013°
• γ: 90°
• Cell volume: 1612.5 ± 0.3 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0314
• Residual factor for significantly intense reflections: 0.0266
• Weighted residual factors for significantly intense reflections: 0.0586
• Weighted residual factors for all reflections included in the refinement: 0.0604
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No