Information card for entry 4123152

Structure parameters

• Formula: C38.5 H82 P6 Si3 W2
• Calculated formula: C38.5 H82 P6 Si3 W2
• Title of publication: σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η(2)-CH2PMe2)H with Phenylsilanes.
• Authors of publication: Zuzek, Ashley A.; Neary, Michelle C.; Parkin, Gerard
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Pages of publication: 141217070549000
• a: 11.276 ± 0.002 Å
• b: 13.112 ± 0.002 Å
• c: 18.316 ± 0.003 Å
• α: 75.844 ± 0.003°
• β: 81.307 ± 0.003°
• γ: 84.182 ± 0.003°
• Cell volume: 2589.8 ± 0.7 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0857
• Residual factor for significantly intense reflections: 0.0411
• Weighted residual factors for significantly intense reflections: 0.056
• Weighted residual factors for all reflections included in the refinement: 0.0648
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No