Information card for entry 4127552

Structure parameters

• Chemical name: {[BP2]Co(dmap)}Si{H2Co[BP3[)
• Formula: C54 H99 B2 Co2 N2 P5 Si
• Calculated formula: C54 H99 B2 Co2 N2 P5 Si
• Title of publication: Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores.
• Authors of publication: Handford, Rex C.; Smith, Patrick W.; Tilley, T. Don
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 22
• Pages of publication: 8769 - 8772
• a: 12.1123 ± 0.0006 Å
• b: 21.5468 ± 0.0011 Å
• c: 22.5752 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5891.7 ± 0.5 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0518
• Residual factor for significantly intense reflections: 0.0413
• Weighted residual factors for significantly intense reflections: 0.0936
• Weighted residual factors for all reflections included in the refinement: 0.0988
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.7288 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No