Information card for entry 4129819

Structure parameters

• Formula: C29 H42 Au Cl F7 N P Sb
• Calculated formula: C29 H42 Au Cl F7 N P Sb
• SMILES: c1(ccc(cc1)F)[Au]([n]1ccccc1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)Cl.F[Sb](F)(F)(F)(F)[F-]
• Title of publication: Phosphonium Formation by Facile Carbon-Phosphorus Reductive Elimination from Gold(III).
• Authors of publication: Kawai, Hiroyuki; Wolf, William J.; DiPasquale, Antonio G.; Winston, Matthew S.; Toste, F. Dean
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2016
• Journal volume: 138
• Journal issue: 2
• Pages of publication: 587 - 593
• a: 10.2613 ± 0.0004 Å
• b: 16.3734 ± 0.0007 Å
• c: 19.8407 ± 0.0008 Å
• α: 90°
• β: 97.3 ± 0.002°
• γ: 90°
• Cell volume: 3306.5 ± 0.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0185
• Residual factor for significantly intense reflections: 0.0155
• Weighted residual factors for significantly intense reflections: 0.0331
• Weighted residual factors for all reflections included in the refinement: 0.0341
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No