Information card for entry 4132282

Structure parameters

• Formula: C30 H60 Cl2 O6 P2 Pt
• Calculated formula: C30 H60 Cl2 O6 P2 Pt
• SMILES: [P]123OCCCCCCCCCCO[P](OCCCCCCCCCCO2)([Pt]1(Cl)Cl)OCCCCCCCCCCO3
• Title of publication: Three-Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH₂) _mCH═CH₂)₃ (X = -, m = 5-10; X = O, m = 3-5): Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes.
• Authors of publication: Joshi, Hemant; Kharel, Sugam; Ehnbom, Andreas; Skopek, Katrin; Hess, Gisela D.; Fiedler, Tobias; Hampel, Frank; Bhuvanesh, Nattamai; Gladysz, John A.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 27
• Pages of publication: 8463 - 8478
• a: 27.366 ± 0.0007 Å
• b: 27.366 ± 0.0007 Å
• c: 26.318 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 17068.9 ± 0.8 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 167
• Hermann-Mauguin space group symbol: R -3 c :H
• Hall space group symbol: -R 3 2"c
• Residual factor for all reflections: 0.1032
• Residual factor for significantly intense reflections: 0.0608
• Weighted residual factors for significantly intense reflections: 0.1546
• Weighted residual factors for all reflections included in the refinement: 0.1813
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No