Information card for entry 4132284

Structure parameters

• Formula: C54 H94 P2 Pt
• Calculated formula: C54 H94 P2 Pt
• SMILES: [Pt]1([P]23CCCCCCCCCCCCCC[P]1(CCCCCCCCCCCCCC3)CCCCCCCCCCCCCC2)(c1ccccc1)c1ccccc1
• Title of publication: Three-Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH₂) _mCH═CH₂)₃ (X = -, m = 5-10; X = O, m = 3-5): Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes.
• Authors of publication: Joshi, Hemant; Kharel, Sugam; Ehnbom, Andreas; Skopek, Katrin; Hess, Gisela D.; Fiedler, Tobias; Hampel, Frank; Bhuvanesh, Nattamai; Gladysz, John A.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 27
• Pages of publication: 8463 - 8478
• a: 13.1005 ± 0.0001 Å
• b: 13.3774 ± 0.0002 Å
• c: 15.5372 ± 0.0002 Å
• α: 77.946 ± 0.001°
• β: 79.853 ± 0.001°
• γ: 82.14 ± 0.001°
• Cell volume: 2607.05 ± 0.06 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0319
• Residual factor for significantly intense reflections: 0.0258
• Weighted residual factors for significantly intense reflections: 0.0592
• Weighted residual factors for all reflections included in the refinement: 0.0618
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No