Information card for entry 4132772

Structure parameters

• Common name: (Cl2)Si{P(cAAC)}2
• Chemical name: dichlorosilabisphosphinidene
• Formula: C47 H70 Cl2 N2 P2 Si
• Calculated formula: C47 H70 Cl2 N2 P2 Si
• Title of publication: Comparison of Two Phosphinidenes Binding to Silicon(IV)dichloride as well as to Silylene.
• Authors of publication: Kundu, Subrata; Sinhababu, Soumen; Siddiqui, Mujahuddin M.; Luebben, Anna V.; Dittrich, Birger; Yang, Tao; Frenking, Gernot; Roesky, Herbert W.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 30
• Pages of publication: 9409 - 9412
• a: 10.7291 ± 0.0007 Å
• b: 10.9423 ± 0.0007 Å
• c: 21.1536 ± 0.0014 Å
• α: 90.135 ± 0.001°
• β: 104.209 ± 0.001°
• γ: 93.207 ± 0.001°
• Cell volume: 2403.4 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0333
• Residual factor for significantly intense reflections: 0.0298
• Weighted residual factors for significantly intense reflections: 0.0754
• Weighted residual factors for all reflections included in the refinement: 0.0781
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No