Information card for entry 4132773

Structure parameters

• Common name: (cAAC)Si{P(cAAC)}2
• Chemical name: bisphosphinidenesilylene
• Formula: C126 H200 N6 P4 Si2
• Calculated formula: C126 H200 N6 P4 Si2
• Title of publication: Comparison of Two Phosphinidenes Binding to Silicon(IV)dichloride as well as to Silylene.
• Authors of publication: Kundu, Subrata; Sinhababu, Soumen; Siddiqui, Mujahuddin M.; Luebben, Anna V.; Dittrich, Birger; Yang, Tao; Frenking, Gernot; Roesky, Herbert W.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• Journal volume: 140
• Journal issue: 30
• Pages of publication: 9409 - 9412
• a: 13.3897 ± 0.0006 Å
• b: 16.8613 ± 0.0007 Å
• c: 28.705 ± 0.0012 Å
• α: 97.348 ± 0.002°
• β: 101.539 ± 0.002°
• γ: 105.097 ± 0.002°
• Cell volume: 6018.5 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0684
• Residual factor for significantly intense reflections: 0.0463
• Weighted residual factors for significantly intense reflections: 0.1075
• Weighted residual factors for all reflections included in the refinement: 0.1195
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No