Information card for entry 4134379

Structure parameters

• Formula: C41 H46 Cl4 Ge2 N4
• Calculated formula: C41 H46 Cl4 Ge2 N4
• SMILES: [Ge]12(Cl)[N](=C(N3C=1N(C(=[N]2c1c(C(C)C)cccc1C(C)C)c1ccccc1)C=C3)c1ccccc1)c1c(cccc1C(C)C)C(C)C.[Ge](Cl)(Cl)Cl
• Title of publication: Ge(0) Compound Stabilized by a Diimino-Carbene Ligand: Synthesis and Ambiphilic Reactivity.
• Authors of publication: Nguyen, Minh Tho; Gusev, Dmitry; Dmitrienko, Anton; Gabidullin, Bulat M.; Spasyuk, Denis; Pilkington, Melanie; Nikonov, Georgii I.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2020
• Journal volume: 142
• Journal issue: 12
• Pages of publication: 5852 - 5861
• a: 8.939 ± 0.0018 Å
• b: 17.513 ± 0.004 Å
• c: 26.736 ± 0.005 Å
• α: 90°
• β: 97.91 ± 0.03°
• γ: 90°
• Cell volume: 4145.7 ± 1.5 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0738
• Residual factor for significantly intense reflections: 0.0705
• Weighted residual factors for significantly intense reflections: 0.2508
• Weighted residual factors for all reflections included in the refinement: 0.2576
• Goodness-of-fit parameter for all reflections included in the refinement: 1.017
• Diffraction radiation wavelength: 0.68879 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No