Information card for entry 4300195

Structure parameters

• Formula: C24 As2 Na4 O93.88 Sn4 W18
• Calculated formula: C24 As2 Na4 O93.88 Sn4 W18
• SMILES: O=[W]1234O[W]567(=O)O[W]89%10(=O)O[W]%11%12(=O)(O2)O[W]2%13(=O)(O8)O[W]8%14%15(=O)O[W]%16(=O)(O3)(O%11)O[W]3%11(=O)(O[W](O1)([O]45[As]([O]9%122)[O]%14%163)(=O)(O6)[O]1[Sn]23([O]=%11)(c4ccccc4)O[Sn]41(c1ccccc1)([O]=7)[O]3[W]135(=O)O[W]679(=O)O[W]%11%12%14(=O)O[W]%16%17%18(=O)O[W]%19%20(=O)(O%11)O[W]%11%21(=O)(O[W]%22(=O)(O%12)(O7)O[W](=O)(O3)(O%11)([O]%21%22[As]([O]%14%17%19)[O]59[W](=O)(O%16)(O6)(O1)=[O]2)=[O]4)=[O][Sn]12(c3ccccc3)(O[Sn]([O]%131)([O]=%15)(c1ccccc1)([O]=%18)[O]%202)[O]=%10)O8.[Na+].O.[Na+].O.O.O.[Na+].O.O.[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: Organotin Derivatives of α-[XIIIW9O33]9- (X = As, Sb) Heteropolytungstates. Solution- and Solid-State Characterization of [{(C6H5Sn)2O}2H(α-AsW9O33)2]9- and [(C6H5Sn)3Na3(α-SbW9O33)2]6-
• Authors of publication: Gerta Sazani; Michael H. Dickman; Michael T. Pope
• Journal of publication: Inorganic Chemistry
• Year of publication: 2000
• Journal volume: 39
• Pages of publication: 939 - 943
• a: 15.272 ± 0.006 Å
• b: 15.303 ± 0.006 Å
• c: 16.76 ± 0.007 Å
• α: 93.59 ± 0.03°
• β: 106.187 ± 0.019°
• γ: 112.23 ± 0.03°
• Cell volume: 3419 ± 3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1157
• Residual factor for significantly intense reflections: 0.1062
• Weighted residual factors for significantly intense reflections: 0.306
• Weighted residual factors for all reflections included in the refinement: 0.3187
• Goodness-of-fit parameter for all reflections included in the refinement: 1.114
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No