Information card for entry 4304874

Structure parameters

• Common name: [Au(C(NHCH3)2)2](AsF6).0.5CO(CH3)2
• Formula: C7.5 H19 As Au F6 N4 O0.5
• Calculated formula: C7.5 H19 As Au F6 N4 O0.5
• Title of publication: Blue or Green Glowing Crystals of the Cation [Au{C(NHMe)2}2]+. Structural Effects of Anions, Hydrogen Bonding, and Solvate Molecules on the Luminescence of a Two-Coordinate Gold(I) Carbene Complex
• Authors of publication: Daniel Rios; David M. Pham; James C. Fettinger; Marilyn M. Olmstead; Alan L. Balch
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 3442 - 3451
• a: 15.6093 ± 0.0008 Å
• b: 15.6093 ± 0.0008 Å
• c: 6.4275 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1566.06 ± 0.17 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 7
• Space group number: 136
• Hermann-Mauguin space group symbol: P 42/m n m
• Hall space group symbol: -P 4n 2n
• Residual factor for all reflections: 0.0218
• Residual factor for significantly intense reflections: 0.0168
• Weighted residual factors for significantly intense reflections: 0.0449
• Weighted residual factors for all reflections included in the refinement: 0.0483
• Goodness-of-fit parameter for all reflections included in the refinement: 1.313
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No