Information card for entry 4304875

Structure parameters

• Common name: [AuL2]AsF6-0.5PhCl
• Formula: C9 H18.5 As Au Cl F6 N4
• Calculated formula: C9 H18.5 As Au Cl0.5 F6 N4
• Title of publication: Blue or Green Glowing Crystals of the Cation [Au{C(NHMe)2}2]+. Structural Effects of Anions, Hydrogen Bonding, and Solvate Molecules on the Luminescence of a Two-Coordinate Gold(I) Carbene Complex
• Authors of publication: Daniel Rios; David M. Pham; James C. Fettinger; Marilyn M. Olmstead; Alan L. Balch
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 3442 - 3451
• a: 11.1918 ± 0.0003 Å
• b: 11.1918 ± 0.0003 Å
• c: 6.4062 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 802.42 ± 0.06 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 7
• Space group number: 131
• Hermann-Mauguin space group symbol: P 42/m m c
• Hall space group symbol: -P 4c 2
• Residual factor for all reflections: 0.0258
• Residual factor for significantly intense reflections: 0.0257
• Weighted residual factors for significantly intense reflections: 0.0817
• Weighted residual factors for all reflections included in the refinement: 0.0819
• Goodness-of-fit parameter for all reflections included in the refinement: 0.835
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No