Information card for entry 4306803

Structure parameters

• Formula: C23.5 H22.5 Cl1.5 F5 N4 O2 Rh S
• Calculated formula: C23.5 H22 Cl1.5 F5 N4 O2 Rh S
• Title of publication: Formation of a Bridging-Imido d6 Rhodium Compound by Nitrene Capture. Insertion and Cycloaddition Reactions
• Authors of publication: Cristina Tejel; Miguel A. Ciriano; Sonia Jiménez; Vincenzo Passarelli; José A. López
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 10220 - 10222
• a: 14.9461 ± 0.0007 Å
• b: 17.8646 ± 0.0008 Å
• c: 19.7834 ± 0.0009 Å
• α: 90°
• β: 97.263 ± 0.001°
• γ: 90°
• Cell volume: 5239.9 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.054
• Residual factor for significantly intense reflections: 0.0496
• Weighted residual factors for significantly intense reflections: 0.1243
• Weighted residual factors for all reflections included in the refinement: 0.1275
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No