Information card for entry 4306806

Structure parameters

• Formula: C36 H44 N2 O6 Rh2 S2
• Calculated formula: C36 H44 N2 O6 Rh2 S2
• SMILES: [Rh]123456([Rh]789%10([N]2(S(=O)(=O)c2ccc(cc2)C)C(=O)N1S(=O)(=O)c1ccc(cc1)C)([c]1([c]7([c]8([c]9([c]%101C)C)C)C)C)C#[O])[c]1([c]3([c]4([c]5([c]61C)C)C)C)C
• Title of publication: Formation of a Bridging-Imido d6 Rhodium Compound by Nitrene Capture. Insertion and Cycloaddition Reactions
• Authors of publication: Cristina Tejel; Miguel A. Ciriano; Sonia Jiménez; Vincenzo Passarelli; José A. López
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 10220 - 10222
• a: 10.176 ± 0.0009 Å
• b: 15.839 ± 0.0014 Å
• c: 22.203 ± 0.002 Å
• α: 90°
• β: 96.785 ± 0.002°
• γ: 90°
• Cell volume: 3553.6 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0934
• Residual factor for significantly intense reflections: 0.0665
• Weighted residual factors for significantly intense reflections: 0.1211
• Weighted residual factors for all reflections included in the refinement: 0.1292
• Goodness-of-fit parameter for all reflections included in the refinement: 1.136
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No