Information card for entry 4306807

Structure parameters

• Formula: C26 H29 N2 O6 Rh S2
• Calculated formula: C26 H29 N2 O6 Rh S2
• SMILES: N1(S(=O)(=O)c2ccc(cc2)C)C(=O)N([Rh]23451(C#[O])[c]1([c]2([c]3([c]5([c]41C)C)C)C)C)S(=O)(=O)c1ccc(cc1)C
• Title of publication: Formation of a Bridging-Imido d6 Rhodium Compound by Nitrene Capture. Insertion and Cycloaddition Reactions
• Authors of publication: Cristina Tejel; Miguel A. Ciriano; Sonia Jiménez; Vincenzo Passarelli; José A. López
• Journal of publication: Inorganic Chemistry
• Year of publication: 2008
• Journal volume: 47
• Pages of publication: 10220 - 10222
• a: 7.846 ± 0.0008 Å
• b: 21.966 ± 0.002 Å
• c: 8.2972 ± 0.0009 Å
• α: 90°
• β: 114.359 ± 0.002°
• γ: 90°
• Cell volume: 1302.7 ± 0.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.0436
• Residual factor for significantly intense reflections: 0.0388
• Weighted residual factors for significantly intense reflections: 0.0931
• Weighted residual factors for all reflections included in the refinement: 0.0954
• Goodness-of-fit parameter for all reflections included in the refinement: 1.155
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No