Information card for entry 4309432

Structure parameters

• Formula: C24 H21 Cl2 N6 Rh
• Calculated formula: C24 H21 Cl2 N6 Rh
• SMILES: [Rh]12(Cl)(Cl)([NH2]c3ccccc3[N]1=Nc1c2cccc1)[NH2]c1ccccc1N=Nc1ccccc1
• Title of publication: Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (NN) Cleavage
• Authors of publication: Jahar lal Pratihar; Nilkamal Maiti; Surajit Chattopadhyay
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 6111 - 6114
• a: 27.216 ± 0.003 Å
• b: 10.2993 ± 0.0008 Å
• c: 20.5772 ± 0.0019 Å
• α: 90°
• β: 122.024 ± 0.004°
• γ: 90°
• Cell volume: 4890.2 ± 0.8 ų
• Cell temperature: 273 ± 2 K
• Ambient diffraction temperature: 273 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0698
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0782
• Weighted residual factors for all reflections included in the refinement: 0.0871
• Goodness-of-fit parameter for all reflections included in the refinement: 0.984
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No